Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii).
نویسندگان
چکیده
The reaction of [Pt(II)(2-phenylpyridine)(acac)] and benzothiazolium bromide yields the N,S-heterocyclic carbene ligand trans to pyridyl while, surprisingly, a very similar N,N-heterocyclic carbene coordinates predominantly trans to the cyclometallated carbon.
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ورودعنوان ژورنال:
- Chemical communications
دوره 44 شماره
صفحات -
تاریخ انتشار 2009